Calculating Corrosion Rate

In summary: But if you had not done that, you would have been correct.In summary, the conversation discusses the calculation of corrosion rate for an iron sample exposed to a corrosive environment. The calculation is based on Faraday's Law and takes into account the surface area of the sample. When both sides of the sample are exposed, the corrosion rate is calculated to be 13.02mm/yr. If only one side is exposed, the corrosion rate remains the same at 13.02mm/yr.
  • #1
FaNgS
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0

Homework Statement



Iron sample with dimensions 10mm x 20mm x 2mm is exposed to a corrosive environment (neglect thickness for surface area). Both sides of the sample are exposed to corrosive environment. Given http://i.imgur.com/tGRw4.jpg"

(a) Calculate corrosion rate mm/y
(b) Calculate corrosion rate if one of the sample surfaces is painted (not in contact with corrosive environment)

Homework Equations



M=56g,
t=3.1536e7 sec/yr
number of electrons taking part n=2
F=96500C
density=7.87g/cm3
A=10*20=200mm2

From Faraday's Law: W=MtI/nF (W=weight loss, I=current in this case corrosion current)

The Attempt at a Solution



(a) From Tafel Plot log(Icorr)=0.05mA/cm2 so Icorr=1.12e-3 A/cm2
I want to convert Icorr to just units of A, but since both surfaces are exposed should I multiply it by double the surface area?

i.e.: Icorr=1.12e-3*200mm2*2*(1cm/10mm)^2 = 4.48e-3 A

substituting in W=Mt*Icorr/nF = 40.99 g/yr

Corrosion Rate CR=W/density*Surface Area

Again I multiplied the Surface Area by 2 because both sides of the Iron sample is exposed

CR=(40.99g/yr)/[(7.87g/cm3)*(200mm2*2)*(1cm/10mm)^3)]=13.02mm/yr

(b) For only one side exposed:
I'm going to use half of Icorr since only 1 side is exposed so Icorr=2.24e-3 A

then W=20.49g/yr

Using only 200mm2 as the surface area

CR=(20.49g/yr)/[(7.87g/cm3)*(200mm2)*(1cm/10mm)^3)]=13.02mm/yr

I get the same corrosion rate...is this correct?

I believe the issue is with the surface area, I'm not sure if it effects the Icorr?
 
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  • #2
I interpret
FaNgS said:
Corrosion Rate CR=W/density*Surface Area
as CR=(W/density)*Surface Area, but in
FaNgS said:
CR=(40.99g/yr)/[(7.87g/cm3)*(200mm2*2)*(1cm/10mm)^3)]
you have CR=W/(density*Surface Area)

Certainly you should not be doubling the area twice. Because of the above error, the two doublings cancelled.
 

1. What is corrosion rate?

Corrosion rate is a measure of the speed at which a material degrades or wears away due to chemical reactions with its environment.

2. How is corrosion rate calculated?

Corrosion rate can be calculated using various methods, but the most common formula is weight loss divided by the product of the metal density, the surface area, and the exposure time.

3. What factors affect corrosion rate?

The rate of corrosion can be influenced by several factors, including the type of metal, the composition and concentration of the corrosive environment, temperature, and presence of impurities or protective coatings.

4. Why is it important to calculate corrosion rate?

Calculating corrosion rate is important for understanding the extent of damage to a material, predicting its lifespan, and implementing measures to prevent or slow down corrosion.

5. Can corrosion rate be reduced or prevented?

Yes, corrosion rate can be reduced or prevented by using corrosion-resistant materials, implementing protective coatings, controlling the environment, and monitoring and maintaining the material's condition.

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