Quantum hybridized orbitals

  • #1
Salamon
35
0
Presentation-Electron bonding 2 atoms.png
Presentation-Electron bonding 4 atoms.jpg


Hello,

I have a few questions about these images that I shared.

1) What does t represent? I am assuming Es is the energy of the atoms before they hybridize, and that t is either the gain or reduction of energy due to the new orbitals that are formed through bonding. Am I way off on this?
2) How does hybridization save energy? I am not seeing why the hybridized energy when there are two atoms is 2Es-2t...It seems that the hybridization can cause the energy to increase or decrease.

I apologize if my questions aren't clear but any insight you can give me in understanding these images would be appreciated.
 
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  • #2
1. your understanding sounds OK to me

2. note that not all orbitals are filled, so the sum of all energies after hybridization is different from the initial n*Es (number of electrons times their initial energy); that in general depends on the number of initial electrons, it is not like it works the same way in every molecule and for every combination of atoms
 

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